Dual-ligand and hard-soft-acid-base strategies to optimize metal-organic framework nanocrystals for stable electrochemical cycling performance.

ABSTRACT: Most metal-organic frameworks (MOFs) hardly maintain their physical and chemical properties after exposure to acidic, neutral, or alkaline aqueous solutions, resulting in insufficient stability, therefore limiting their applications. Thus, the design and synthesis of stable size/morphology-controlled MOF nanocrystals is critical but challenging. In this study, dual-ligand and hard-soft-acid-base strategies were used to fabricate a variety of 3D pillared-layer [Ni(thiophene-2,5-dicarboxylate)(4,4^'-bipyridine)]_n MOF nanocrystals (1D nanofibers, 2D nanosheets and 3D aggregates) with controllable morphology by varying the concentration of 4,4^'-bipyridine and thus controlling the crystal growth direction. Owing to the shorter ion diffusion length, enhanced elect

SUBMITTER: Zheng S 

PROVIDER: S-EPMC9362764 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature