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Photocatalytic stannylation of white phosphorus.

ABSTRACT: Organophosphorus compounds (OPCs) are highly important chemicals, finding numerous applications in both academia and industry. Herein we describe a simple photocatalytic method for the stannylation of white phosphorus (P₄) using a cheap, commercially-available distannane, (Bu₃Sn)₂, and anthraquinone as a simple photocatalyst. Subsequent 'one pot' transformation of the resulting stannylated monophosphine intermediate (Bu₃Sn)₃P provides direct, convenient and versatile access to valuable OPCs such as acylated phosphines and tetraalkylphosphonium salts.

SUBMITTER: Till M

PROVIDER: S-EPMC9362875 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature

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Photocatalytic stannylation of white phosphorus.

Till Marion M Cammarata Jose J Wolf Robert R Scott Daniel J DJ

Chemical communications (Cambridge, England) 20220809 64

Organophosphorus compounds (OPCs) are highly important chemicals, finding numerous applications in both academia and industry. Herein we describe a simple photocatalytic method for the stannylation of white phosphorus (P4) using a cheap, commercially-available distannane, (Bu3Sn)2, and anthraquinone as a simple photocatalyst. Subsequent 'one pot' transformation of the resulting stannylated monophosphine intermediate (Bu3Sn)3P provides direct ...[more]

PMID: 35861572

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