Synthesis and characterization of tung oil-based UV curable for three-dimensional printing resins.
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ABSTRACT: Using tung oil as the raw material, a new bio-based prepolymer was successfully synthesized by reacting with acrylic-modified rosin (β-acryloyl nutrient ethyl) ester (ARA)/acrylic-2-hydroxyethyl ester (HEA) followed by the use of the above composite material as the matrix and then reacting with the active diluent (2-HEMA, TPGDA) and the photoinitiator TPO and Irgacure1173 to successfully synthesize a new type of bio-based prepolymer-acrylate-epoxy tung oil polypolymer (AETP). The tung oil monomer before and after the epoxy formation was compared by proton NMR spectroscopy, and the chemical structure of AETP was analyzed by Fourier transform spectroscopy. Tung oil has an acid value of 1.5 mg KOH per g, an epoxy value of 5.38%, an iodine value of 11.28 g/100 g, and a refractive index of n
SUBMITTER: Zhao Z
PROVIDER: S-EPMC9364080 | biostudies-literature | 2022 Aug
REPOSITORIES: biostudies-literature
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