Self-Assembling Oligo(2-oxazoline) Organogelators for the Encapsulation and Slow Release of Bioactive Volatiles.

ABSTRACT: Herein, we report a class of distinctive supramolecular nanostructures in situ-generated from the cationic ring-opening polymerization of a particular 2-oxazoline monomer, i.e., 2-(N-tert-butyloxycarbonylaminomethyl)-2-oxazoline (Ox1). Driven by side-chain hydrogen bonding between neighboring molecules and van der Waals interactions, the growing oligomers of Ox1 precipitate in the form of macroscopic platelets when the degree of polymerization reaches 5-7. A similar self-assembly occurred in the block copolymerization of 2-ethyl-2-oxazoline (EtOx) or 2-pentyl-2-oxazoline (PeOx) and Ox1 as the second monomer. These polymeric aggregates were found to disassemble into rod-like nanoparticles under appropriate conditions, and to form stable organogels in some polar solvents like d

SUBMITTER: Lv Y 

PROVIDER: S-EPMC9366986 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature