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A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation.

ABSTRACT: A series of Au(I)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the isolation of a rather unique and highly distorted cis-type dihydride platinum(II) structure.

SUBMITTER: Hidalgo N 

PROVIDER: S-EPMC9367266 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature

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A highly constrained <i>cis</i>-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation.

Hidalgo Nereida N   de la Cruz-Martínez Felipe F   Martín M Trinidad MT   Nicasio M Carmen MC   Campos Jesús J  

Chemical communications (Cambridge, England) 20220811 65

A series of Au(I)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the isolation of a rather unique and highly distorted <i>cis</i>-type dihydride platinum(II) structure. ...[more]

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