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Electrochemical Site-Selective Alkylation of Azobenzenes with (Thio)Xanthenes.

ABSTRACT: Herein, we first report an electrochemical methodology for the site-selective alkylation of azobenzenes with (thio)xanthenes in the absence of any transition metal catalyst or external oxidant. A variety of groups are compatible with this electrochemical alkylation, which furnishes the products in moderate to good yields.

SUBMITTER: Zhong Q

PROVIDER: S-EPMC9370205 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature

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Electrochemical Site-Selective Alkylation of Azobenzenes with (Thio)Xanthenes.

Zhong Qiang Q Gao Hui H Wang Pei-Long PL Zhou Chao C Miao Tao T Li Hongji H

Molecules (Basel, Switzerland) 20220804 15

Herein, we first report an electrochemical methodology for the site-selective alkylation of azobenzenes with (thio)xanthenes in the absence of any transition metal catalyst or external oxidant. A variety of groups are compatible with this electrochemical alkylation, which furnishes the products in moderate to good yields. ...[more]

PMID: 35956916

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