An excellent deep-ultraviolet birefringent material based on [BO₂]^∞ infinite chains.

ABSTRACT: Birefringent materials play indispensable roles in modulating the polarization of light and are vital in the laser science and technology. Currently, the design of birefringent materials operating in the deep-ultraviolet region (DUV, λ ≤200 nm) is still a great challenge. In this work, we developed a new DUV birefringent crystal LiBO₂ based on [BO₂]^∞ infinite chains in the Li-B-O system, which simultaneously achieves the shortest UV cutoff edge (164 nm) and the largest birefringence (≥0.168 at 266 nm) among all the reported borate-based DUV birefringent materials. Single crystals of LiBO₂ with dimensions up to Ø55 × 34 mm³ were grown by the Czochralski method, providing access to large-sized single crystal with low cost. Moreover, it has a high laser damage threshold and stable physicochemical properties. These outstanding characters unambiguously support that LiBO₂ can be an excellent birefringent material for DUV application.

SUBMITTER: Zhang F 

PROVIDER: S-EPMC9372186 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature