Subphthalocyanine capsules: molecular reactors for photoredox transformations of fullerenes.

ABSTRACT: The internal cavity formed by a dimeric subphthalocyanine (SubPc) capsule (SubPc₂Pd₃, 2), ensembled by coordination of pyridyl substituents in the monomeric SubPc 1 to Pd centers, has proved an optimal space for the complexation of C₆₀ fullerene. Taking advantage of the intense absorption of green light of the SubPc component at around 550 nm, we have tested different green-light induced photoredox addition reactions over the double bonds of guest C₆₀. Both addition of amine radicals, generated by reductive quenching of the excited state of 2 by aromatic trimethylsilylamines, and addition of trifluoroethyl radicals, obtained from oxidative quenching of the photosensitizer, have successfully taken place with good yields in the 2:C₆₀ hos

SUBMITTER: Moreno-Simoni M 

PROVIDER: S-EPMC9384690 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature