Structural evolution and strain generation of derived-Cu catalysts during CO₂ electroreduction.

ABSTRACT: Copper (Cu)-based catalysts generally exhibit high C₂₊ selectivity during the electrochemical CO₂ reduction reaction (CO₂RR). However, the origin of this selectivity and the influence of catalyst precursors on it are not fully understood. We combine operando X-ray diffraction and operando Raman spectroscopy to monitor the structural and compositional evolution of three Cu precursors during the CO₂RR. The results indicate that despite different kinetics, all three precursors are completely reduced to Cu(0) with similar grain sizes (~11 nm), and that oxidized Cu species are not involved in the CO₂RR. Furthermore, Cu(OH)₂- and Cu₂(OH)₂CO₃-derived Cu exhibit considerable tensile strain (0.43%~0.5

SUBMITTER: Lei Q 

PROVIDER: S-EPMC9388520 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature