Synthesis, dielectric, magnetic, and photoluminescence properties of two new hybrid rare-earth double perovskites.

ABSTRACT: Two new organic-inorganic hybrid double perovskites (R3HQ)₄CsSm(NO₃)₈ (1) (R3HQ = (R)-(-)-3-quinuclidinol) and (R3HQ)₄CsEu(NO₃)₈ (2) were synthesized and characterized. Compounds 1 and 2 exhibit obvious phase transitions at 379 and 375 K, respectively, confirmed by differential scanning calorimetry (DSC) and variable temperature powder X-ray diffraction. The rapid switching between high- and low-dielectric states makes it a typical dielectric material with a switchable dielectric constant for thermal stimulus response. Furthermore, 1 and 2 show attractive photoluminescence and paramagnetic behavior, and the fluorescence quantum yield of 2 reached 14.6%. These results sh

SUBMITTER: Wang ZJ 

PROVIDER: S-EPMC9389020 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature