Fluorescent molecularly imprinted polymer particles for glyphosate detection using phase transfer agents.

ABSTRACT: In this work, molecular imprinting was combined with direct fluorescence detection of the pesticide Glyphosate (GPS). Firstly, the solubility of highly polar GPS in organic solvents was improved by using lipophilic tetrabutylammonium (TBA⁺) and tetrahexylammonium (THA⁺) counterions. Secondly, to achieve fluorescence detection, a fluorescent crosslinker containing urea-binding motifs was used as a probe for GPS-TBA and GPS-THA salts in chloroform, generating stable complexes through hydrogen bond formation. The GPS/fluorescent dye complexes were imprinted into 2-3 nm fluorescent molecularly imprinted polymer (MIP) shells on the surface of sub-micron silica particles using chloroform as porogen. Thus, the MIP binding behavior could be easily evaluated by fluorescence ti

SUBMITTER: Kimani M 

PROVIDER: S-EPMC9391380 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature