Ultramicroporous material based parallel and extended paraffin nano-trap for benchmark olefin purification.

ABSTRACT: Selective paraffin capture from olefin/paraffin mixtures could afford high-purity olefins directly, but suffers from the issues of low separation selectivity and olefin productivity. Herein, we report an ultramicroporous material (PCP-IPA) with parallel-aligned linearly extending isophthalic acid units along the one-dimensional channel, realizing the efficient production of ultra-high purity C₂H₄ and C₃H₆ (99.99%). The periodically expanded and parallel-aligned aromatic-based units served as a paraffin nano-trap to contact with the exposed hydrogen atoms of both C₂H₆ and C₃H₈, as demonstrated by the simulation studies. PCP-IPA exhibits record separation selectivity of 2.48 and separation potential of 1.

SUBMITTER: Zhang P 

PROVIDER: S-EPMC9395351 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature