Double-Bilayer polar nanoregions and Mn antisites in (Ca, Sr)₃Mn₂O₇.

ABSTRACT: The layered perovskite Ca₃Mn₂O₇ (CMO) is a hybrid improper ferroelectric candidate proposed for room temperature multiferroicity, which also displays negative thermal expansion behavior due to a competition between coexisting polar and nonpolar phases. However, little is known about the atomic-scale structure of the polar/nonpolar phase coexistence or the underlying physics of its formation and transition. In this work, we report the direct observation of double bilayer polar nanoregions (db-PNRs) in Ca_2.9Sr_0.1Mn₂O₇ using aberration-corrected scanning transmission electron microscopy (S/TEM). In-situ TEM heating experiments show that the db-PNRs can exist up to 650 °C. Electron energy loss spectroscopy (EELS) studies coupled with first-principles calculations demonstrate that the stabilization mechanism of the db-PNRs is directly related to an Mn oxidation state change (from 4+ to 2+), which is linked to the presence of Mn antisite defects. These findings open the door to manipulating phase coexistence and achieving exotic properties in hybrid improper ferroelectric.

SUBMITTER: Miao L 

PROVIDER: S-EPMC9395386 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature