Tannic acid assisted metal-chelate interphase toward highly stable Zn metal anodes in rechargeable aqueous zinc-ion batteries.

ABSTRACT: Aqueous zinc-ion batteries (AZIBs) have attracted extensive attention because of their eco-friendliness, intrinsic safety, and high theoretical capacity. Nevertheless, the long-standing Zn anode issues such as dendrite growth, hydrogen evolution, and passivation greatly restrict the further development of AZIBs. Herein, a metal-chelate interphase with high Zn affinity is constructed on the Zn metal surface (TA@Zn) via dipping metallic Zn into a tannic acid (TA) solution to address the aforementioned problems. Benefiting from the abundant hydrophilic and zincophilic phenolic hydroxyl groups of TA molecules, the metal-chelate interphase shows strong attraction for Zn²⁺ ions, guiding uniform zinc deposition as well as decreasing Zn²⁺ migration barrier. Therefore, the TA@

SUBMITTER: Hu N 

PROVIDER: S-EPMC9399369 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature