1-(Azidomethyl)-5H-Tetrazole: A Powerful New Ligand for Highly Energetic Coordination Compounds.

ABSTRACT: Highly energetic 1-(azidomethyl)-5H-tetrazole (AzMT, 3) has been synthesized and characterized. This completes the series of 1-(azidoalkyl)-5H-tetrazoles represented by 1-(azidoethyl)-5H-tetrazole (AET) and 1-(azidopropyl)-5H-tetrazole (APT). AzMT was thoroughly analyzed by single-crystal X-ray diffraction experiments, elemental analysis, IR spectroscopy and multinuclear (¹ H, ¹³ C, ¹⁴ N, ¹⁵ N) NMR measurements. Several energetic coordination compounds (ECCs) of 3d metals (Mn, Fe, Cu, Zn) and silver in combination with anions such as (per)chlorate, mono- and dihydroxy-trinitrophenolate were prepared, giving insight into the coordination behavior of AzMT as a ligand. The synthesized ECCs were also analyzed by X-ray diffraction experiments, element

SUBMITTER: Kofen M 

PROVIDER: S-EPMC9400890 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature