Entropy Enhanced Perovskite Oxide Ceramic for Efficient Electrochemical Reduction of Oxygen to Hydrogen Peroxide.
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ABSTRACT: The electrochemical oxygen reduction reaction (ORR) offers a most promising and efficient route to produce hydrogen peroxide (H2 O2 ), yet the lack of cost-effective and high-performance electrocatalysts have restricted its practical application. Herein, an entropy-enhancement strategy has been employed to enable the low-cost perovskite oxide to effectively catalyze the electrosynthesis of H2 O2 . The optimized Pb(NiWMnNbZrTi)1/6 O3 ceramic is available on a kilogram-scale and displays commendable ORR activity in alkaline media with high selectivity over 91 % across the wide potential range for H2 O2 including an outstanding degradation property for organic dyes through the Fenton process. The exception
SUBMITTER: Chen Z
PROVIDER: S-EPMC9400899 | biostudies-literature | 2022 May
REPOSITORIES: biostudies-literature
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