A Planar Five-Membered Aromatic Ring Stabilized by Only Two π-Electrons.

ABSTRACT: Many chemicals known today are partially or fully aromatic, since a ring framework experiences additional stabilization through the delocalization of π-electrons. While aromatic rings with equal numbers of π-electrons and ring atoms such as benzene are particularly stable, those with the minimally required two π-electrons are very rare and yet remain limited to three- and four-membered rings if not stabilized in the coordination sphere of heavy metals. Here we report the facile synthesis of a dipotassium cyclopentagallene, a unique example of a five-membered aromatic ring stabilized by only two π-electrons. Single-crystal X-ray diffraction revealed a planar Ga₅ ring with almost equal gallium-gallium bond lengths, which together with computational and spectroscopic data confirm i

SUBMITTER: Kysliak O 

PROVIDER: S-EPMC9401857 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature