Mercury isotope evidence for Arctic summertime re-emission of mercury from the cryosphere.

ABSTRACT: During Arctic springtime, halogen radicals oxidize atmospheric elemental mercury (Hg⁰), which deposits to the cryosphere. This is followed by a summertime atmospheric Hg⁰ peak that is thought to result mostly from terrestrial Hg inputs to the Arctic Ocean, followed by photoreduction and emission to air. The large terrestrial Hg contribution to the Arctic Ocean and global atmosphere has raised concern over the potential release of permafrost Hg, via rivers and coastal erosion, with Arctic warming. Here we investigate Hg isotope variability of Arctic atmospheric, marine, and terrestrial Hg. We observe highly characteristic Hg isotope signatures during the summertime peak that reflect re-emission of Hg deposited to the cryosphere during spring. Air mass back trajectories

SUBMITTER: Araujo BF 

PROVIDER: S-EPMC9402541 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature