High-Temperature Gaseous Reaction of Cesium with Siliceous Thermal Insulation: The Potential Implication to the Provenance of Enigmatic Fukushima Cesium-Bearing Material.

ABSTRACT: Here, we report an investigation of the gas-solid reaction between cesium hydroxide (CsOH) and siliceous (calcium silicate) thermal insulation at high temperature, which is postulated as the origin for the formation mechanism of cesium-bearing material emitted from the Fukushima Daiichi nuclear power plant. A developed reaction furnace consisting of two heating compartments was used to study the reaction at temperatures of 873, 973, and 1073 K. Under the influence of hydrogen-steam atmospheric conditions (H₂/H₂O = 0.2), the reaction between cesium hydroxide vapor and solid thermal insulation was confirmed to occur at temperatures of 973 and 1073 K with the formation of dicalcium silicate (Ca₂SiO₄) and cesium aluminum silicate (CsAlSiO₄

SUBMITTER: Rizaal M 

PROVIDER: S-EPMC9404493 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature