Phase Transformations and Phase Segregation during Potassiation of Sn _x P _y Anodes.

ABSTRACT: K-ion batteries (KIBs) have the potential to offer a cheaper alternative to Li-ion batteries (LIBs) using widely abundant materials. Conversion/alloying anodes have high theoretical capacities in KIBs, but it is believed that electrode damage from volume expansion and phase segregation by the accommodation of large K-ions leads to capacity loss during electrochemical cycling. To date, the exact phase transformations that occur during potassiation and depotassiation of conversion/alloying anodes are relatively unexplored. In this work, we synthesize two distinct compositions of tin phosphides, Sn₄P₃ and SnP₃, and compare their conversion/alloying mechanisms with solid-state nuclear magnetic resonance (SSNMR) spectroscopy, powder X-ray diffraction (XRD), and

SUBMITTER: Ells AW 

PROVIDER: S-EPMC9404545 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature