Dynamic Supramolecular Polymers Based on Zinc Bis(diorganophospate)s: Synthesis, Structure and Transformations in Solid State and Solutions.

ABSTRACT: The synthesis, structure and some properties of coordination polymers composed of linear zinc bis(diorganophospate)s (ZnDOPs) with a general formula of Zn[O₂P(OR)₂]₂ (where R = CH₃, C₂H₅, n-C₄H₉, or 2-ethylhexyl group) are described. Hybrid (co)polymers obtained by different procedures were characterized by means of powder XRD, DSC, SEM, TGA coupled with mass spectrometry of the evolved gases and rheological measurements, as well as FTIR and NMR techniques. The morphology, thermal transformations and solubility of ZnDOPs strongly depend on the type of organic substituent in the O₂P(OR)₂ ligands and the thermal history of the sample. Because of this, one can obtain highly cry

SUBMITTER: Debowski M 

PROVIDER: S-EPMC9412697 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature