A Rapid Thermal Absorption Rate and High Latent Heat Enthalpy Phase Change Fiber Derived from Bio-Based Low Melting Point Copolyesters.

ABSTRACT: A series of poly(butylene adipate-co-hexamethylene adipate) (PBHA) copolymers with different content of 1,4-cyclohexanedimethanol (CHDM) was synthesized via one-step melt polymerization. The PBHA copolymer with 5 mol% CHDM (PBHA-C5) exhibited a low melting point (T_m) and high enthalpy of fusion (∆H_m) of 35.7 °C and 43.9 J g^-1, respectively, making it a potential candidate for an ambient temperature adjustment textile phase change material (PCM). Polybutylene terephthalate (PBT) was selected as the matrix and blended at different weight ratios of PBHA-C5, and the blended samples showed comparable T_m and ∆H_m after three cycles of cooling and reheating, indicating good maintenance of their phase changing ability. Samples were then

SUBMITTER: Lan TY 

PROVIDER: S-EPMC9413292 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature