Chemo-Biocascade Reactions Enabled by Metal-Organic Framework Micro-Nanoreactor.

ABSTRACT: The one-pot combination of biocatalytic and chemocatalytic reactions represents an economically and ecologically attractive concept in the emerging cascade processes for manufacturing. The mutual incompatibility of biocatalysis and chemocatalysis, however, usually causes the deactivation of catalysts, the mismatching of reaction dynamic, and further challenges their integration into concurrent chemo-biocascades. Herein, we have developed a convenient strategy to construct versatile functional metal-organic framework micro-nanoreactors (MOF-MNRs), which can realize not only the encapsulation and protection of biocatalysts but also the controllable transmission of substances and the mutual communication of the incompatible chemo-biosystems. Importantly, the MOFs serving as the shell of MNRs

SUBMITTER: Zhang J 

PROVIDER: S-EPMC9414180 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature