Photocatalytic Activity of TiO₂/g-C₃N₄ Nanocomposites for Removal of Monochlorophenols from Water.

ABSTRACT: This research employed g-C₃N₄ nanosheets in the hydrothermal synthesis of TiO₂/g-C₃N₄ hybrid photocatalysts. The TiO₂/g-C₃N₄ heterojunctions, well-dispersed TiO₂ nanoparticles on the g-C₃N₄ nanosheets, are effective photocatalysts for the degradation of monochlorophenols (MCPs: 2-CP, 3-CP, and 4-CP) which are prominent water contaminants. The removal efficiency of 2-CP and 4-CP reached 87% and 64%, respectively, after treatment of 25 ppm CP solutions with the photocatalyst (40TiO₂/g-C₃N₄, 1 g/L) and irradiation with UV-Vis light. Treatment of CP solutions with g-C₃N₄ nanosheets or TiO₂ alone in conjunction with irradiation gave removal efficiencies lower than 50%, which suggests the two act synergically to enhance the photocatalytic activity of the 40TiO₂/g-C₃N₄ nanocomposite. Superoxide and hydroxyl radicals are key active species produced during CP photodegradation. In addition, the observed nitrogen and Ti³⁺ defects and oxygen vacancies in the TiO₂/g-C₃N₄ nanocomposites may improve the light-harvesting ability of the composite and assist preventing rapid electron-hole recombination on the surface, enhancing the photocatalytic performance. In addition, interfacial interactions between the MCPs (low polarity) and thermally exfoliated carbon nitride in the TiO₂/g-C₃N₄ nanocomposites may also enhance MCP degradation.

SUBMITTER: Kobkeatthawin T 

PROVIDER: S-EPMC9414261 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature