Heterobimetallic Ru(II)/M (M = Ag⁺, Cu²⁺, Pb²⁺) Complexes as Photosensitizers for Room-Temperature Gas Sensing.

ABSTRACT: This work is devoted to the investigation of heterobimetallic Ru(II) complexes as photosensitizers for room-temperature photoactivated In₂O₃-based gas sensors. Nanocrystalline In₂O₃ was synthesized by the chemical precipitation method. The obtained In₂O₃ matrix has a single-phase bixbyite structure with an average grain size of 13-14 nm and a specific surface area of 72 ± 3 m²/g. The synthesis of new ditope ligands with different coordination centers, their ruthenium complexes, and the preparation of heterobimetallic complexes with various cations of heavy and transition metals (Ag⁺, Pb²⁺, or Cu²⁺) is reported. The heterobimetallic Ru(II) complexes were deposited onto the surface o

SUBMITTER: Nasriddinov A 

PROVIDER: S-EPMC9415935 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature