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Co₃O₄ Nanopetals Grown on the Porous CuO Network for the Photocatalytic Degradation.

ABSTRACT: Designing a novel photocatalytic composite for the efficient degradation of organic dyes remains a serious challenge. Herein, the multi-layered Co₃O₄@NP-CuO photocatalyst with unique features, i.e., the self-supporting, hierarchical porous network as well as the construction of heterojunction between Co₃O₄ and CuO, are synthesized by dealloying-electrodeposition and subsequent thermal treatment techniques. It is found that the interwoven ultrathin Co₃O₄ nanopetals evenly grow on the nanoporous CuO network (Co₃O₄@NP-CuO). The three-dimensional (3D) hierarchical porous structure for the catalyst provides more surface area to act as active sites and facilitates the absorption of visible light in the photodegradation reaction. Compared with the commercial CuO and Co₃O₄ powders, the newly designed Co₃O₄@NP-CuO composite exhibits superior photodegradation performance for RhB. The enhanced performance is mainly due to the construction of heterojunction of Co₃O₄/CuO, greatly promoting the efficient carrier separation for photocatalysis. Furthermore, the possible photocatalytic mechanism is analyzed in detail. This work provides a promising strategy for the fabrication of a new controllable heterojunction to improve photocatalytic activity.

SUBMITTER: Sun Y

PROVIDER: S-EPMC9416053 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature

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Co3O4 Nanopetals Grown on the Porous CuO Network for the Photocatalytic Degradation.

Sun Yuntao Y Wang Can C Qin Shengyao S Pan Fengda F Li Yongyan Y Wang Zhifeng Z Qin Chunling C

Nanomaterials (Basel, Switzerland) 20220818 16

Designing a novel photocatalytic composite for the efficient degradation of organic dyes remains a serious challenge. Herein, the multi-layered Co3O4@NP-CuO photocatalyst with unique features, i.e., the self-supporting, hierarchical porous network as well as the construction of heterojunction between Co3O4 and CuO, are synthesized by dealloying-electrodeposition and subsequent thermal treatment techniques. It is found that the interwoven ultrathin Co<s ...[more]

PMID: 36014718

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Project description:In this work, we report the facile, environmentally friendly, room-temperature (RT) synthesis of porous CuO nanosheets and their application as a photocatalyst to degrade an organic pollutant/food dye using NaBH4 as the reducing agent in an aqueous medium. Ultrahigh-resolution field effect scanning electron microscopy images of CuO displayed a broken nanosheet-like (a length of ∼160 nm, a width of ∼65 nm) morphology, and the lattice strain was estimated to be ∼1.24 × 10-3 using the Williamson-Hall analysis of X-ray diffraction plots. Owing to the strong quantum size confinement effect, CuO nanosheets resulted in an optical energy band gap of ∼1.92 eV, measured using Tauc plots of the ultraviolet-visible (UV-vis) spectrum, resulting in excellent photocatalytic efficiency. The RT synthesized CuO catalyst showed a high Brunauer-Emmet-Teller surface area of 30.88 ± 0.2313 m2/g (a correlation coefficient of 0.99972) with an average Barrett-Joyner-Halenda pore size of ∼20.385 nm. The obtained porous CuO nanosheets exhibited a high crystallinity of 73.5% with a crystallite size of ∼12 nm and was applied as an efficient photocatalyst for degradation of the organic pollutant/food dye, Allura Red AC (AR) dye, as monitored by UV-vis spectrophotometric analysis and evidenced by a color change from red to colorless. From UV-vis spectra, CuO nanosheets exhibited an efficient and ultrafast photocatalytic degradation efficiency of ∼96.99% for the AR dye in an aqueous medium within 6 min at RT. According to the Langmuir-Hinshelwood model, photodegradation reaction kinetics followed a pseudo-first-order reaction with a rate constant of k = 0.524 min-1 and a half-life (t 1/2) of 2.5 min for AR dye degradation in the aqueous medium. The CuO nanosheets showed an outstanding recycling ability for AR degradation and would be highly favorable and an efficient catalyst due to the synergistic effect of high adsorption capability and photodegradation of the food dye.

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Co₃O₄ Nanopetals Grown on the Porous CuO Network for the Photocatalytic Degradation.

Publications

Co<sub>3</sub>O<sub>4</sub> Nanopetals Grown on the Porous CuO Network for the Photocatalytic Degradation.

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