Influence of Cu doping on the local electronic and magnetic properties of ZnO nanostructures.

ABSTRACT: In this paper, we report the existence of defect induced intrinsic room-temperature ferromagnetism (RTFM) in Cu doped ZnO synthesized via a facile sol-gel route. The wurtzite crystal structure of ZnO remained intact up to certain Cu doping concentrations under the present synthesis environment as confirmed by the Rietveld refined X-ray diffraction pattern with the average crystallite size between 35 and 50 nm. Field emission scanning electron microscopy reveals the formation of bullet-like morphologies for pure and Cu doped ZnO. Diffuse reflectance UV-vis shows a decrease in the energy band gap of ZnO on Cu doping. Further, these ZnO samples exhibit strong visible photoluminescence in the region of 500-700 nm associated with defects/vacancies. Near-edge X-ray absorption fine-structu

SUBMITTER: Bhardwaj R 

PROVIDER: S-EPMC9417303 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature