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NiCo₂O₄ nanoparticles inlaid on sulphur and nitrogen doped and co-doped rGO sheets as efficient electrocatalysts for the oxygen evolution and methanol oxidation reactions.

ABSTRACT: The present work depicts the fabrication of NiCo₂O₄ decorated on rGO, and doped and co-doped rGO and its electrocatalytic activity towards the oxygen evolution reaction and methanol oxidation reaction. The NiCo₂O₄ catalyst with S-doped rGO outperformed the other catalysts, indicating that the sulphur atoms attached on rGO possess low oxophilicity and optimum free energy. This results in facile adsorption of the intermediate products formed during the OER and a rapid release of O₂ molecules. The same catalyst requires an overpotential of 1.51 V vs. RHE to attain the benchmark current density value of 10 mA cm^-2 and shows a Tafel slope of 57 mV dec^-1. It also reveals outstanding stability during its operation for 10 h with a minimum loss in potential. On the other hand, NiCo₂O₄/S,N-rGO reveals superior activity with high efficiency and stability in catalyzing methanol oxidation. The catalyst delivered a low onset potential of 0.12 V vs. Hg/HgO and high current density of 203.4 mA cm^-2 after addition of 0.5 M methanol, revealing the outstanding performance of the electrocatalyst.

SUBMITTER: Rebekah

PROVIDER: S-EPMC9417605 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature

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NiCo2O4 nanoparticles inlaid on sulphur and nitrogen doped and co-doped rGO sheets as efficient electrocatalysts for the oxygen evolution and methanol oxidation reactions.

Rebekah Viswanathan C C Ponpandian N N

Nanoscale advances 20210330 11

The present work depicts the fabrication of NiCo2O4 decorated on rGO, and doped and co-doped rGO and its electrocatalytic activity towards the oxygen evolution reaction and methanol oxidation reaction. The NiCo2O4 catalyst with S-doped rGO outperformed the other catalysts, indicating that the sulphur atoms attached on rGO possess low oxophilicity and optimum free energy. This results in facile adsorption of the intermediate products formed during the O ...[more]

PMID: 36133652

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Project description:Fabrication of ZnO nanoparticles (NPs) via green process has received enormous attention for its application in biomedicine. Here, a simple and cost-effective green route is reported for the synthesis of ZrO2-doped ZnO/reduced graphene oxide nanocomposites (ZnO/ZrO2/rGO NCs) exploiting ginger rhizome extract. Our aim was to improve the anticancer performance of ZnO/ZrO2/rGO NCs without toxicity to normal cells. The preparation of pure ZnO NPs, ZnO/ZrO2 NCs, and ZnO/ZrO2/rGO NCs was confirmed by transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), photoluminescence (PL), and dynamic light scattering (DLS). XRD spectra of ZnO/ZrO2/rGO NCs exhibited two distinct sets of diffraction peaks, ZnO wurtzite structure, and ZrO2 phases (monoclinic + tetragonal). The SEM and TEM data show that ZrO2-doped ZnO particles were uniformly distributed on rGO sheets with the excellent quality of lattice fringes without alterations. PL spectra intensity and particle size of ZnO decreased after ZrO2-doping and rGO addition. DLS data demonstrated that green prepared samples show excellent colloidal stability in aqueous suspension. Biological results showed that ZnO/ZrO2/rGO NCs display around 3.5-fold higher anticancer efficacy in human lung cancer (A549) and breast cancer (MCF7) cells than ZnO NPs. A mechanistic approach suggested that the anticancer response of ZnO/ZrO2/rGO NCs was mediated via oxidative stress evident by the induction of the intracellular reactive oxygen species level and the reduction of the glutathione level. Moreover, green prepared nanostructures display good cytocompatibility in normal cell lines; human lung fibroblasts (IMR90) and breast epithelial (MCF10A) cells. However, the cytocompatibility of ZnO/ZrO2/rGO NCs in normal cells was better than those of pure ZnO NPs and ZnO/ZrO2 NCs. Augmented anticancer potential and improved cytocompatibility of ZnO/ZrO2/rGO NCs was due to ginger extract mediated beneficial synergism between ZnO, ZrO2, and rGO. This novel investigation emphasizes the significance of medicinal herb mediated ZnO-based NCs synthesis for biomedical research.

Dataset Information

NiCo₂O₄ nanoparticles inlaid on sulphur and nitrogen doped and co-doped rGO sheets as efficient electrocatalysts for the oxygen evolution and methanol oxidation reactions.

Publications

NiCo<sub>2</sub>O<sub>4</sub> nanoparticles inlaid on sulphur and nitrogen doped and co-doped rGO sheets as efficient electrocatalysts for the oxygen evolution and methanol oxidation reactions.

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