Dynamics in hydrated inorganic nanotubes studied by neutron scattering: towards nanoreactors in water.

ABSTRACT: Water dynamics in inorganic nanotubes is studied by neutron scattering technique. Two types of aluminosilicate nanotubes are investigated: one is completely hydrophilic on the external and internal surfaces (IMO-OH) while the second possesses an internal cavity which is hydrophobic due to the replacement of Si-OH bonds by Si-CH₃ ones (IMO-CH₃), the external surface being still hydrophilic. The samples have internal radii equal to 7.5 and 9.8 Å, respectively. By working under well-defined relative humidity (RH) values, water dynamics in IMO-OH was revealed by quasi-elastic spectra as a function of the filling of the interior of the tubes. When one water monolayer is present on the inner surface of the tube, water molecules can jump between neighboring Si-OH sites on th

SUBMITTER: Le Caer S 

PROVIDER: S-EPMC9417873 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature