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Ti _n+1C _n MXenes with fully saturated and thermally stable Cl terminations.

ABSTRACT: MXenes are a rapidly growing family of 2D materials that exhibit a highly versatile structure and composition, allowing for significant tuning of the materials properties. These properties are, however, ultimately limited by the surface terminations, which are typically a mixture of species, including F and O that are inherent to the MXene processing. Other and robust terminations are lacking. Here, we apply high-resolution scanning transmission electron microscopy (STEM), corresponding image simulations and first-principles calculations to investigate the surface terminations on MXenes synthesized from MAX phases through Lewis acidic melts. The results show that atomic Cl terminates the synthesized MXenes, with mere residual presence of other termination species. Furthermore, in situ STEM-electron energy loss spectroscopy (EELS) heating experiments show that the Cl terminations are stable up to 750 °C. Thus, we present an attractive new termination that widely expands the MXenes' functionalization space and enables new applications.

SUBMITTER: Lu J

PROVIDER: S-EPMC9417890 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature

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Ti n+1C n MXenes with fully saturated and thermally stable Cl terminations.

Lu J J Persson I I Lind H H Palisaitis J J Li M M Li Y Y Chen K K Zhou J J Du S S Chai Z Z Huang Z Z Hultman L L Eklund P P Rosen J J Huang Q Q Persson P O Å POÅ

Nanoscale advances 20190725 9

MXenes are a rapidly growing family of 2D materials that exhibit a highly versatile structure and composition, allowing for significant tuning of the materials properties. These properties are, however, ultimately limited by the surface terminations, which are typically a mixture of species, including F and O that are inherent to the MXene processing. Other and robust terminations are lacking. Here, we apply high-resolution scanning transmission electron microscopy (STEM), corresponding image si ...[more]

PMID: 36133532

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Project description:Because of the high specific surface area, excellent electronic conductivity, facile Li diffusion, and rich functional groups, Ti2C-based MXenes have been widely used to improve the electrochemical property of lithium-sulfur batteries. The complex surface functionalization (such as -OH, -S, -F, and -O) of MXenes boosts the performance but also causes controversies about the favorable functionalized surface in the electrochemical reaction during the charge and discharge process. In the present work, a theoretical study based on density functional theory has been carried out to clarify the favorable functionalized surface by comparing pristine Ti2C and -OH-, -S-, -F-, and -O-functionalized Ti2C surfaces from the aspects of adsorption ability, electronic conductivity, and kinetic conversion ability. It is found that compared with severe polysulfide deformation on pristine Ti2C and Ti2C(OH)2 surfaces, Ti2CO2, Ti2CS2, and Ti2CF2 have effective polysulfide adsorption. Ti2CO2 has the largest surface adsorption energy, followed by Ti2CS2, and Ti2CF2 is the weakest. Meanwhile, the narrow-band gap semiconductor property of Ti2CO2 during adsorption indicates worse electronic conductivity than metallic Ti2CS2 and Ti2CF2. In addition, for the kinetic conversion ability, the Ti2CS2 surface has the fastest polysulfide conversion and Li diffusion, followed by Ti2CF2, and Ti2CO2 represents the slowest conversion and diffusion. Accordingly, because of the medium binding energy, good electronic conductivity, and fast polysulfide conversion and Li diffusion, Ti2CS2 is revealed to be the favorable functionalized surface. More importantly, the origin for the Ti2CS2 surface with medium adsorption ability represents the fastest polysulfide conversion, and Li diffusion is further clarified. The great affinity of the Ti2CS2 surface to the product Li2S leads to facile polysulfide conversion. The uniform charge distribution on the Ti2CS2 surface contributes to the fast Li diffusion.

Dataset Information

Ti _n+1C _n MXenes with fully saturated and thermally stable Cl terminations.

Publications

Ti <sub><i>n</i>+1</sub>C <sub><i>n</i></sub> MXenes with fully saturated and thermally stable Cl terminations.

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