Thermomechanically controlled fluorescence anisotropy in thin films of InP/ZnS quantum dots.

ABSTRACT: Macroscopic scale sources of polarized light play a fundamental role in designing light-emitting devices. In this communication we report the formation of nano- and macro-scale ordered, layered assemblies of InP/ZnS quantum dots (QDs) exhibiting fluorescence anisotropy (FA), as well as thermo- and mechano-responsive properties. The long-range organization of small, quasi-isotropic nanoparticles was achieved by introducing liquid crystal molecules to the surface of QDs, without the need to use an organic matrix. Melting/crystallization of the ligand at 95 deg. C translated to a reversible reconfiguration of QDs thin film between 2D layered and body-centered cubic structures, characteristic for a temperature range below and above the melting point, respectively. The low-temperature, layered

SUBMITTER: Parzyszek S 

PROVIDER: S-EPMC9418115 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature