Dataset Information

Polarisation tuneable piezo-catalytic activity of Nb-doped PZT with low Curie temperature for efficient CO₂ reduction and H₂ generation.

ABSTRACT: The reduction of CO₂ into useful hydrocarbon chemicals has attracted significant attention in light of the depletion in fossil resources and the global demand for sustainable sources of energy. In this paper, we demonstrate piezo-catalytic electrochemical reduction of CO₂ by exploiting low Curie temperature, T _c ∼ 38 °C, Nb-doped lead zirconate titanate (PZTN) piezoelectric particulates. The large change in spontaneous polarisation of PZTN due to the acoustic pressures from to the application of ultrasound in the vicinity of the T _c creates free charges for CO₂ reduction. The effect of applied acoustic power, particulate agglomeration and the impact of T _c on piezo-catalytic performance are explored. By optimization of the piezo-catalytic effect a promising piezo-catalytic CO₂ reduction rate of 789 μmol g^-1 h^-1 is achieved, which is much larger than the those obtained from pyro-catalytic effects. This efficient and polarisation tunable piezo-catalytic route has potential to promote the development of CO₂ reduction via the utilization of vibrational energy for environmental improvement.

SUBMITTER: Zhang Y

PROVIDER: S-EPMC9418403 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Polarisation tuneable piezo-catalytic activity of Nb-doped PZT with low Curie temperature for efficient CO2 reduction and H2 generation.

Zhang Yan Y Thuy Phuong Pham Thi PT Hoang Duy Nguyen Phuc NP Roake Eleanor E Khanbareh Hamideh H Hopkins Margaret M Zhou Xuefan X Zhang Dou D Zhou Kechao K Bowen Chris C

Nanoscale advances 20210215 5

The reduction of CO2 into useful hydrocarbon chemicals has attracted significant attention in light of the depletion in fossil resources and the global demand for sustainable sources of energy. In this paper, we demonstrate piezo-catalytic electrochemical reduction of CO2 by exploiting low Curie temperature, T c ∼ 38 °C, Nb-doped lead zirconate titanate (PZTN) piezoelectric particulates. The large change in spontaneous polarisation of PZTN due to the acous ...[more]

PMID: 36132863

Similar Datasets

Project description:Lead zirconate titanate (PZT) films with high Nb concentrations (6-13 mol%) were grown by chemical solution deposition. In concentrations up to 8 mol% Nb, the films self-compensate the stoichiometry; single phase films were grown from precursor solutions with 10 mol% PbO excess. Higher Nb concentrations induced multi-phase films unless the amount of excess PbO in the precursor solution was reduced. Phase pure perovskite films were grown with 13 mol% excess Nb with the addition of 6 mol% PbO. Charge compensation was achieved by creating lead vacancies when decreasing excess PbO level; using Kroger-Vink notation, NbTi• are ionically compensated by VPb″ to maintain charge neutrality in heavily Nb-doped PZT films. With Nb doping, films showed suppressed {100} orientation, the Curie temperature decreased, and the maximum in the relative permittivity at the phase transition broadened. The dielectric and piezoelectric properties were dramatically degraded due to increased quantity of the non-polar pyrochlore phase in multi-phase films; εr reduced from 1360 ± 8 to 940 ± 6, and the remanent d33,f value decreased from 112 to 42 pm/V when increasing the Nb concentration from 6 to 13 mol%. Property deterioration was corrected by decreasing the PbO level to 6 mol%; phase pure perovskite films were attained. εr and the remanent d33,f increased to 1330 ± 9 and 106 ± 4 pm/V, respectively. There was no discernable difference in the level of self-imprint in phase pure PZT films with Nb doping. However, the magnitude of the internal field after thermal poling at 150 °C increased significantly; the level of imprint was 30 kV/cm and 11.5 kV/cm in phase pure 6 mol% and 13 mol% Nb-doped films, respectively. The absence of mobile VO••, coupled with the immobile VPb″ in 13 mol% Nb-doped PZT films, leads to lower internal field formation upon thermal poling. For 6 mol% Nb-doped PZT films, the internal field formation was primarily governed by (1) the alignment of (VPb″-VO•• )x and (2) the injection and subsequent electron trapping by Ti4+. For 13 mol% Nb-doped PZT films, hole migration between VPb″ controlled internal field formation upon thermal poling.

Dataset Information

Polarisation tuneable piezo-catalytic activity of Nb-doped PZT with low Curie temperature for efficient CO₂ reduction and H₂ generation.

Publications

Polarisation tuneable piezo-catalytic activity of Nb-doped PZT with low Curie temperature for efficient CO<sub>2</sub> reduction and H<sub>2</sub> generation.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets