Highly luminescent and stable quasi-2D perovskite quantum dots by introducing large organic cations.

ABSTRACT: Herein, ultra-stable quasi-two-dimensional perovskite quantum dots (quasi-2D PQDs) are synthesized by introducing the butylamine cation (BA⁺) into the methylamine lead bromide perovskite (MAPbBr₃). By reducing the dimensionality of the perovskite structure, the quasi-2D perovskite (BA)₂(MA) _x-1Pb _x Br_3x+1 presents higher luminescence efficiency and better environmental stability than traditional 3D perovskites, which is mainly because the dimensionality-reduced perovskite has higher exciton binding energy and formation energy. Under an optimal MA : BA ratio of 1 : 1, the quasi-2D perovskite exhibits about four times higher luminescence efficiency (PLQY = 49.44%) than pristine MAPbBr₃; meanwhil

SUBMITTER: Wang J 

PROVIDER: S-EPMC9418505 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature