Metal-enhanced fluorescence of dyes with quadrupole surface plasmon resonance of silver nanoparticles.

ABSTRACT: Silver colloidal films (SCFs) composed of homogeneous 60-220 nm silver nanoparticles were synthesized for optimal fluorescence enhancement of chromophores with the dipole and quadrupole surface plasmons. The fluorescence enhancements with the SCFs of three chromophores, 4-(dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran, 4-dimethylamino-4'-nitrobiphenyl, and coumarin 343 whose emission spectra are centered distinctively in the 470-560 nm wavelength range were compared. Fluorescence enhancements and lifetime changes were investigated via time-resolved fluorescence spectroscopy. The spectral overlap between the chromophore's emission and the dipole or quadrupole surface plasmon resonance (SPR) bands determined the fluorescence enhancements with the SCFs. The dipol

SUBMITTER: Lee D 

PROVIDER: S-EPMC9418669 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature