Spontaneous selective deposition of iron oxide nanoparticles on graphite as model catalysts.

ABSTRACT: Iron oxide nanomaterials participate in redox processes that give them ideal properties for their use as earth-abundant catalysts. Fabricating nanocatalysts for such applications requires detailed knowledge of the deposition and growth. We report the spontaneous deposition of iron oxide nanoparticles on HOPG in defect areas and on step edges from a metal precursor solution. To study the nucleation and growth of iron oxide nanoparticles, tailored defects were created on the surface of HOPG using various ion sources that serve as the target sites for iron oxide nucleation. After solution deposition and annealing, the iron oxide nanoparticles were found to nucleate and coalesce at 400 °C. AFM revealed that the particles on the sp³ carbon sites enabled the nanoparticles to aggregate

SUBMITTER: de Alwis C 

PROVIDER: S-EPMC9418714 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature