Observation of a novel double layer surface oxide phase on Ni₃Al(111) at low temperature.

ABSTRACT: The Ni₃Al(111) surface was characterized during oxidation within the temperature range of 690-800 K by in situ scanning tunneling microscopy (STM), low energy electron diffraction (LEED) and auger electron spectroscopy (AES). Within this temperature range oxygen dosing always leads to the formation of a surface aluminum oxide layer while Ni atoms remain in their metallic state. The temperature however, affects the kinetics and the structure of the grown oxides. Above 790 K the known (√67 × √67)R12.2° double layer oxide grows, which consists of two Al-O layers. Oxygen dosing at the lower temperature of 740 ± 10 K leads to a single layer oxide with only one Al-O plane. The lattice mismatch of the aligned oxygen and substrate lattices induce a (7 × 7) moiré pattern of this s

SUBMITTER: Ma X 

PROVIDER: S-EPMC9418789 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature