Adsorption of charged anisotropic nanoparticles at oil-water interfaces.

ABSTRACT: The adsorption of nanoparticles at fluid interfaces is of profound importance in the field of nanotechnology. Recent developments aim at pushing the boundaries beyond spherical model particles towards more complex shapes and surface chemistries, with particular interest in particles of biological origin. Here, we report on the adsorption of charged, shape-anisotropic cellulose nanocrystals (CNCs) for a wide range of oils with varying chemical structure and polarity. CNC adsorption was found to be independent of the chain length of aliphatic n-alkanes, but strongly dependent on oil polarity. Surface pressures decreased for more polar oils due to lower particle adsorption energies. Nanoparticles were increasingly wetted by polar oils, and interparticle Coulomb interactions across the

SUBMITTER: Bergfreund J 

PROVIDER: S-EPMC9419606 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature