A hybrid upconversion nanoprobe for ratiometric detection of aliphatic biogenic amines in aqueous medium.

ABSTRACT: We fabricated an inorganic-organic hybrid upconversion nanoprobe for the ratiometric detection of aliphatic biogenic amines in water. The hybrid nanoprobe comprises a thiophene-based acceptor-π-donor-π-acceptor organic fluorescent dye, TDPM, and near-infrared light-absorbing upconversion nanoparticles (UCNPs). The organic dye was loaded into a mesoporous silica-coated UCNP (UCNP@mSiO₂) matrix to circumvent the issues of water insolubility and higher energy excitation. Yb³⁺ and Tm³⁺-doped UCNPs exhibited dual emission bands at 475 and 645 nm upon excitation with a 980 nm laser. The significant spectral overlap between the absorption and the emission bands of TDPM and UCNPs, respectively, at 475 nm led to resonance energy transfer (RET) from the UCNPs to TDPM

SUBMITTER: Jaiswal S 

PROVIDER: S-EPMC9419630 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature