The mixture effect on ionic selectivity and permeability of nanotubes.

ABSTRACT: Ion-selective nanotubes have great potential in applications such as ion separation, desalination, and power generation. However, their performance is often limited by the deteriorated selectivity in mixed salt solutions. To reveal the underlying mechanism of the mixture effect on ion transport through nanotubes, we perform molecular dynamics (MD) simulations on ion transport through carbon nanotubes (CNTs) and polymer nanopores with a pore diameter of ∼1 nm and a charge density of -1 e nm^-2. Based on the simulation results, when a single salt solution is replaced by a mixed salt solution, the ionic selectivity drops as the permeability of higher permeable ions decreases much greater than that of lower permeable ions. This is because the adsorption of lower permeable ions on the

SUBMITTER: Wang M 

PROVIDER: S-EPMC9419827 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature