Tailoring the defects of sub-100 nm multipodal titanium nitride/oxynitride nanotubes for efficient water splitting performance.

ABSTRACT: Deciphering the photocatalytic-defect relationship of photoanodes can pave the way towards the rational design for high-performance solar energy conversion. Herein, we rationally designed uniform and aligned ultrathin sub-100 nm multipodal titanium nitride/oxynitride nanotubes (TiON _x NTs) (x = 2, 4, and 6 h) via the anodic oxidation of Ti-foil in a formamide-based electrolyte followed by annealing under ammonia gas for different durations. XPS, XPS imaging, Auger electron spectra, and positron annihilation spectroscopy disclosed that the high nitridation rate induced the generation of a mixture of Ti-nitride and oxynitride with various vacancy-type defects, including monovacancies, vacancy clusters, and a few voids inside TiO _x NTs. These

SUBMITTER: Eid K 

PROVIDER: S-EPMC9419868 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature