Isolation and structural comparison of Ru^II-dnp complexes [dnp = 2,6-bis-(1,8-naphthyridin-2-yl)pyridine] with axially or equatorially coordinating NCS ligands.

ABSTRACT: The mol-ecular and crystal structures of two ruthenium(II) complexes, viz. cis-aqua-[2,6-bis-(1,8-naphthyridin-2-yl)pyridine-κ³ N,N',N''](thio-cyanato-κN)(tri-phen-yl-phosphine-κP)ruthenium(II) hexa-fluorido-phosphate-acetone-water (1/0.5/1), [Ru(NCS)(C₂₁H₁₃N₅)(C₁₈H₁₅P)(H₂O)]PF₆·0.5C₃H₆O·H₂O (I) and trans-[2,6-bis-(1,8-naphthyridin-2-yl)pyridine-κ³'N,N',N'']bis-(pyridine-κN)(thiocyanato-κN)ruthenium(II) thio-cyanate, [Ru(NCS)(C₂₁H₁₃N₅)(C₅H₅N)₂]NCS (II), with an N-coordinating thio-cyanato group and a tridentate p

SUBMITTER: Takase T 

PROVIDER: S-EPMC9431777 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature