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Incorporation of in situ generated 3,3'-(sulfane-diyl)bis-(1-methyl-1,3-imidazolidine-2-thione) into a one-dimensional Cu^I coordination polymer with sulfur-bridged {Cu^I ₄S₁₀} _n central cores.

ABSTRACT: The reaction of [Cu(CH₃CN)₄](BF₄) with 1-methyl-1,3-imidazolidine-2-thione {SC₃H₄(NMe)NH}, under aerobic conditions at room temperature, yielded an unusual one-dimensional coordination polymer, namely, catena-poly[[[(1-meth-yl-1,3-imidazolidine-2-thione-κS)copper(I)]-μ-(1-methyl-1,3-imidazolidine-2-thione)-κ² S:S-copper(I)-μ-[3,3'-(sulfanedi-yl)bis-(1-methyl-1,3-imidazolidine-2-thione)]-κ⁵ S,S',S'':S,S''] bis-(tetra-fluorido-borate)], {[Cu₂(C₄H₈N₂S)₂(C₈H₁₄N₄S₃)](BF₄)₂} _n or [Cu₄(κ⁵:L

SUBMITTER: Lobana TS

PROVIDER: S-EPMC9431798 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature

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Incorporation of in situ generated 3,3'-(sulfane-diyl)bis-(1-methyl-1,3-imidazolidine-2-thione) into a one-dimensional Cu^I coordination polymer with sulfur-bridged {Cu^I ₄S₁₀} _n central cores.

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Incorporation of in situ generated 3,3'-(sulfane-diyl)bis-(1-methyl-1,3-imidazolidine-2-thione) into a one-dimensional CuI coordination polymer with sulfur-bridged {CuI 4S10} n central cores.

OmicsDI is part of the ELIXIR infrastructure

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Incorporation of in situ generated 3,3'-(sulfane-diyl)bis-(1-methyl-1,3-imidazolidine-2-thione) into a one-dimensional Cu^I coordination polymer with sulfur-bridged {Cu^I ₄S₁₀} _n central cores.