Large contribution of fossil-derived components to aqueous secondary organic aerosols in China.

ABSTRACT: Incomplete understanding of the sources of secondary organic aerosol (SOA) leads to large uncertainty in both air quality management and in climate change assessment. Chemical reactions occurring in the atmospheric aqueous phase represent an important source of SOA mass, yet, the effects of anthropogenic emissions on the aqueous SOA (aqSOA) are not well constrained. Here we use compound-specific dual-carbon isotopic fingerprints (δ¹³C and Δ¹⁴C) of dominant aqSOA molecules, such as oxalic acid, to track the precursor sources and formation mechanisms of aqSOA. Substantial stable carbon isotope fractionation of aqSOA molecules provides robust evidence for extensive aqueous-phase processing. Contrary to the paradigm that these aqSOA compounds are largely biogenic, radioca

SUBMITTER: Xu B 

PROVIDER: S-EPMC9433442 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature