Dual electronic effects achieving a high-performance Ni(II) pincer catalyst for CO₂ photoreduction in a noble-metal-free system.

ABSTRACT: A carbazolide-bis(NHC) Ni^II catalyst (1; NHC, N-heterocyclic carbene) for selective CO₂ photoreduction was designed herein by a one-stone-two-birds strategy. The extended π-conjugation and the strong σ/π electron-donation characteristics (two birds) of the carbazolide fragment (one stone) lead to significantly enhanced activity for photoreduction of CO₂ to CO. The turnover number (TON) and turnover frequency (TOF) of 1 were ninefold and eightfold higher than those of the reported pyridinol-bis(NHC) Ni^II complex at the same catalyst concentration using an identical Ir photosensitizer, respectively, with a selectivity of ∼100%. More importantly, an organic dye was applied to displace the Ir photosensitizer to develop a noble-me

SUBMITTER: Huang HH 

PROVIDER: S-EPMC9436338 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature