Critical ionic transport across an oxygen-vacancy ordering transition.

ABSTRACT: Phase transition points can be used to critically reduce the ionic migration activation energy, which is important for realizing high-performance electrolytes at low temperatures. Here, we demonstrate a route toward low-temperature thermionic conduction in solids, by exploiting the critically lowered activation energy associated with oxygen transport in Ca-substituted bismuth ferrite (Bi_1-xCa_xFeO_3-δ) films. Our demonstration relies on the finding that a compositional phase transition occurs by varying Ca doping ratio across x_Ca ≃ 0.45 between two structural phases with oxygen-vacancy channel ordering along <100> or <110> crystal axis, respectively. Regardless of the atomic-scale irregularity in defect distribution at the doping ratio, the activat

SUBMITTER: Lim JS 

PROVIDER: S-EPMC9437025 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature