Metal-free enantiomorphic perovskite [dabcoH₂]²⁺[H₃O]⁺Br^- ₃ and its one-dimensional polar polymorph.

ABSTRACT: The structure and stoichiometry of a new metal-free and ammonium-free compound [dabcoH₂]²⁺H₃O⁺Br^- ₃ (where [dabcoH₂]²⁺ = 1,4-di-aza-bicyclo-[2.2.2]octane dication) correspond to the general formula ABX ₃ characteristic of perovskites. In enantiomorphic trigonal polymorph α of [dabcoH₂]²⁺H₃O⁺Br^- ₃, the corner-sharing [H₃O]Br₆ octahedra combine into a 3D framework embedding [dabcoH₂]²⁺ dications in pseudo-cubic cages. In the more dense polymorph β, the face-sharing [H₃O]Br₆ octahedra form 1D polyanionic columns separated by [dabcoH₂]²⁺

SUBMITTER: Budzianowski A 

PROVIDER: S-EPMC9438492 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature