PH Jumps in a Protic Ionic Liquid Proceed by Vehicular Proton Transport.

ABSTRACT: The dynamics of excess protons in the protic ionic liquid (PIL) ethylammonium formate (EAF) have been investigated from femtoseconds to microseconds using visible pump mid-infrared probe spectroscopy. The pH jump following the visible photoexcitation of a photoacid (8-hydroxypyrene-1,3,6-trisulfonic acid trisodium salt, HPTS) results in proton transfer to the formate of the EAF. The proton transfer predominantly (∼70%) occurs over picoseconds through a preformed hydrogen-bonded tight complex between HPTS and EAF. We investigate the longer-range and longer-time-scale proton-transport processes in the PIL by obtaining the ground-state conjugate base (RO^-) dynamics from the congested transient-infrared spectra. The spectral kinetics indicate that the protons diffuse only a few solv

SUBMITTER: Maiti S 

PROVIDER: S-EPMC9442784 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature