Infrared Spectroscopy on Equilibrated High-Density Amorphous Ice.

ABSTRACT: High-density (HDA) and low-density amorphous ices (LDA) are believed to be counterparts of the high- and low-density liquid phases of water, respectively. In order to better understand how the vibrational modes change during the transition between the two solid states, we present infrared spectroscopy measurements, following the change of the decoupled OD-stretch (v_OD) (∼2460 cm^-1) and OH-combinational mode (v_OH + v₂, v_OH + 2v_R) (∼5000 cm^-1). We observe a redshift from HDA to LDA, accompanied with a drastic decrease of the bandwidth. The hydrogen bonds are stronger in LDA, which is caused by a change in the coordination number and number of water molec

SUBMITTER: Karina A 

PROVIDER: S-EPMC9442797 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature