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Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility.

ABSTRACT: Electrochemical hydrogenation of enones using a proton-exchange membrane reactor is described. The reduction of enones proceeded smoothly under mild conditions to afford ketones or alcohols. The reaction occurred chemoselectively with the use of different cathode catalysts (Pd/C or Ir/C).

SUBMITTER: Mitsudo K

PROVIDER: S-EPMC9443409 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature

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Electrochemical hydrogenation of enones using a proton-exchange membrane reactor: selectivity and utility.

Mitsudo Koichi K Inoue Haruka H Niki Yuta Y Sato Eisuke E Suga Seiji S

Beilstein journal of organic chemistry 20220819

Electrochemical hydrogenation of enones using a proton-exchange membrane reactor is described. The reduction of enones proceeded smoothly under mild conditions to afford ketones or alcohols. The reaction occurred chemoselectively with the use of different cathode catalysts (Pd/C or Ir/C). ...[more]

PMID: 36105727

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