General Strategy toward Hydrophilic Single Atom Catalysts for Efficient Selective Hydrogenation.

ABSTRACT: Well dispersible and stable single atom catalysts (SACs) with hydrophilic features are highly desirable for selective hydrogenation reactions in hydrophilic solvents towards important chemicals and pharmaceutical intermediates. A general strategy is reported for the fabrication of hydrophilic SACs by cation-exchange approach. The cation-exchange between metal ions (M = Ni, Fe, Co, Cu) and Na⁺ ions introduced in the skeleton of metal oxide (TiO₂ or ZrO₂ ) nanoshells plays the key role in forming M₁ /TiO₂ and M₁ /ZrO₂ SACs, which efficiently prevents the aggregation of the exchanged metal ions. The as-obtained SACs are highly dispersible and stable in hydrophilic solvents including alcohol and water, which greatly f

SUBMITTER: Ling Y 

PROVIDER: S-EPMC9443439 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature